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The devil's in the disequilibrium: multi-component analysis of dissolved carbon and oxygen changes under a broad range of forcings...

...in a general circulation model

Abstract.

"The complexity of dissolved gas cycling in the ocean presents a challenge for mechanistic understanding and can hinder model intercomparison. One helpful approach is the conceptualization of dissolved gases as the sum of multiple, strictly defined components. Here we decompose dissolved inorganic carbon (DIC) into four components: saturation (DICsat), disequilibrium (DICdis), carbonate (DICcarb), and soft tissue (DICsoft). The cycling of dissolved oxygen is simpler, but can still be aided by considering O2, O2sat, and O2dis. [...]"

Source: Biogeosciences
Authors: Sarah Eggleston and Eric D. Galbraith
DOI: 10.5194/bg-15-3761-2018

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Diapycnal dissolved organic matter supply into the upper Peruvian oxycline

Abstract.

"The Eastern Tropical South Pacific (ETSP) hosts the Peruvian upwelling system, which represents one of the most productive areas in the world ocean. High primary production followed by rapid heterotrophic utilization of organic matter supports the formation of one of the most intense oxygen minimum zones (OMZ) in the world ocean where dissolved oxygen (O2) concentrations reach well below 1 µmol kg−1. The high productivity leads to an accumulation of dissolved organic matter (DOM) in the surface layers that may serve as a substrate for heterotrophic respiration.  [...]"

Source: Biogeosciences
Authors: lexandra N. Loginova et al.
DOI: 10.5194/bg-2018-284

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Drivers and mechanisms of ocean deoxygenation

Abstract.

"Direct observations indicate that the global ocean oxygen inventory is decreasing. Climate models consistently confirm this decline and predict continuing and accelerating ocean deoxygenation. However, current models (1) do not reproduce observed patterns for oxygen changes in the ocean’s thermocline; (2) underestimate the temporal variability of oxygen concentrations and air–sea fluxes inferred from time-series observations; and (3) generally simulate only about half the oceanic oxygen loss inferred from observations. [...]"

Source: Nature Geoscience
Authors: Andreas Oschlies et al.
DOI: 10.1038/s41561-018-0152-2

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A Giant Blob of Floodwater From Harvey Is Still Moving Through the Gulf

"The rain began on August 25, and it would fall, remarkably, for four more days. We know now that Hurricane Harvey dumped as much as 60 inches of rain over parts of Texas. Twenty trillion gallons in all. The equivalent of the entire Chesapeake Bay. Enough to push the Earth’s crust down two centimeters. [...]

What oceanographers do know about the interface of freshwater and ocean comes from studying rivers that naturally empty into the sea. The key is density. Because freshwater lacks dissolved salt, it is less dense and floats atop seawater. It becomes a barrier between the air and the ocean water, which can have nasty consequences. “The freshwater sitting on the salty water cuts off the oxygen from the atmosphere getting into the ocean, and then you get the dead zone,” says Steve DiMarco [...]"

Source: The Atlantic

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The ocean’s vital skin: Towards an integrated understanding of the sea surface microlayer

Abstract.

"Despite the huge extent of the ocean’s surface, until now relatively little attention has been paid to the sea surface microlayer (SML) as the ultimate interface where heat, momentum and mass exchange between the ocean and the atmosphere takes place. Via the SML, large-scale environmental changes in the ocean such as warming, acidification, deoxygenation and eutrophication potentially influence cloud formation, precipitation and the global radiation balance. Due to the deep connectivity between biological, chemical and physical processes, studies of the SML may reveal multiple sensitivities to global and regional changes.  [...]"

Source: Frontiers in Marine Science
Authors: Anja Engel et al.
DOI: 10.3389/fmars.2017.00165

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Impacts of ENSO on air-sea oxygen exchange: observations and mechanisms

Abstract.

"Models and observations of Atmospheric Potential Oxygen (APO ≃ O2 + 1.1*CO2) are used to investigate the influence of El Niño Southern Oscillation (ENSO) on air-sea O2 exchange. An atmospheric transport inversion of APO data from the Scripps flask network shows significant interannual variability in tropical APO fluxes that is positively correlated with the Niño3.4 index, indicating anomalous ocean outgassing of APO during El Niño. Hindcast simulations of the Community Earth System Model (CESM) and the Institut Pierre-Simon Laplace (IPSL) model show similar APO sensitivity to ENSO, differing from the Geophysical Fluid Dynamic Laboratory (GFDL) model, which shows an opposite APO response. [...]"

Source: Global Biochemical Cycles
Authors: Yassir A. Eddebbar et al.
DOI: 10.1002/2017GB005630

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